|
This is the fifth in a series of pages on dental ceramics. The
material presented on each page is designed to stand alone, but a real
understanding of this material relies on knowledge presented on the pages
that precede it. Terms on this page that will be unfamiliar to the casual reader
have been defined there. This series represents a mini course in ceramics
for the beginner, and persons seriously interested in gaining a basic working
knowledge of dental ceramics are advised to take the time to start at the
beginning.
|
Dentists and allied dental professionals often
seek CE courses from ADA CERP recognized providers to fulfill their
CE requirements for re-licensure. Most state and provincial
licensing boards will accept CE credits issued by ADA CERP
recognized providers. In the spring of 2003, the FDI World
Dental Federation became the first internationally based CE provider
to be granted ADA CERP recognition.
Please contact your state board directly for their specific rules
and regulations. Most states approve supervised self-study courses
that are ADA CERP accredited.
Those interested in receiving 3 continuing
education credits for this course may take the 20 question test at a
cost of $39 and receive their certificate immediately by clicking
here. |
Table of contents (page 5)
What is a core?
In dental ceramics, a core can be loosely defined as a rigid
and durable structure designed to closely fit one or more abutment teeth and
used as a framework to support a tooth colored, translucent esthetic veneer.
The majority of core materials are opaque and therefore cannot be used
without an esthetic veneer. This is not true in every case as a few core
materials are esthetic enough to stand alone as tooth colored restorations
without the addition of a feldspathic veneer.
The first esthetic frameworks were gold crowns and bridges with
mechanical retention used to retain an acrylic veneer. These were
invented in the 1940's. The first true porcelain-bearing core structures were made of
cast gold alloys that displayed metallic oxides on their surfaces. The
metal oxides on the surface of the framework made it possible to chemically
bond a porcelain veneer directly to the metal. Metallic frameworks
gave support to the otherwise weak porcelain making possible the production
of both crowns and multi unit bridges. The porcelain fused to metal
technique was invented in the late 1950's
and patented in 1962. PFM restorations are discussed in detail
on my Dental Alloys
page.
The aluminous core
The first all-porcelain core was fabricated in1965.
This was the
aluminous core, and it remained the workhorse of all-porcelain
anterior crowns from that time until the early 1990's when the first
glass ceramic
restorations entered the market. Aluminous cores are fabricated on a
refractory die by a dental laboratory technician using the
powder condensation technique
technique. The first layers of the frit are compacted tightly against
the die since the die tends to draw the water out of the slurry. The
porcelain remains on the die through all subsequent firings and
additions of frit. After the the main body of the crown has
been fully fired, the technician switches to feldspathic frits to complete
the buccal esthetic veneer. While the flexural strength of "plain" feldspathic
porcelain is around 50-60 MPa (Mega Pascals), that of an aluminous core is
between 120-130MPa. Even with the increase in strength, aluminous
cores still are not strong enough to support multi unit bridges.
Ceramic cores
No glass?...No
bond!!
Porcelain Jacket crowns, Glass ceramic
crowns and veneers, and aluminous core crowns are all variations of
feldspathic porcelains. As such, they are made of glass infused with
various inclusions and thus may be
etched and bonded to enamel and dentin in
the same way that composite restorations are bonded. However,
the restorations in the following sections are built on ceramic cores that
do not contain glass. Therefore, etching these restorations would
accomplish nothing. Resin bonding is not necessary when cementing these restorations
to the teeth. They
are cemented using zinc phosphate or glass ionomer cements, the same
as the dentist uses for PFM crowns and bridges, although many
dentists still etch and bond the tooth structure under the core.
Glass
infused ceramic core systems
Aluminous cores are made by adding alumina to the glass system before the frit-sintering
stage. This method of manufacture limits the addition of alumina to no
more than 40-50% by volume. On the other hand, glass infused ceramic
cores are built using pure alumina, spinel or zirconia which is sintered
PRIOR to the introduction of the glass. Thus these cores achieve
a much higher proportion of refractory crystalline filler than is possible
with traditional aluminous core techniques.
In-Ceram by Vita was the first high strength alumina core
system, achieving approximately 85% by volume of sintered alumina in
its core. These are fabricated using a slip casting process.
A slip is simply a clay mixed with enough water to make it a creamy
texture. In-Ceram uses
a slip made of water mixed with a suspension of finely ground alumina
particles. The slip is used to coat a porous die in the shape of the final coping.
In slip casting, the die is designed to absorb the water in the slip.
This causes the suspended ceramic particles to condense tightly against the
die. The "green" ceramic body is fired on the die
at 1120°C for 10 hours. This temperature is too
low to completely fuse the silica, but it produces a
sintered
framework with a fairly dense structure and little or no shrinkage. The
sintered body by itself is not especially strong, but it has a porous texture and when infused with a low
viscosity glass, it creates a thin coping with great
strength. This coping is then overlain with feldspathic dental ceramic
to fill out the form of the tooth. This creates a somewhat opaque restoration that
can be used on molars. The strength of this core material is not quite
sufficient to be used as a framework for posterior bridges. This type
of core is known as a glass infused ceramic core. An In-Ceram
all-alumina core's
flexural strength is about 500 MPa.
| It should be emphasized that
the listed flexural strengths for this, and the other cores shown on this
page are for the cores themselves. The flexural strength of the
finished appliance, including both the core and the applied veneer is
considerably less due to the inherent low strength of the veneered
porcelain. |
Vita has created other glass infused
core systems replacing the sintered alumina with other oxides and oxide
mixtures. In-Ceram-Spinel (ICS) uses spinel (MgAl2O4) in sintered form to
produce a more translucent and esthetic version of its original In-Ceram at the cost of
slightly reduced flexural strength (~350MPa). ICS is indicated for
anterior crowns. In-Ceram--Zirconia (ICZ) uses
a mixture of aumina and zirconium oxide crystals to produce a glass infused
ceramic that is even stronger than the original In-Ceram (~700MPa).
ICZ is used for posterior crowns and bridges, but not indicated for anterior
restorations due to its opacity.
Pure alumina cores
|
Pure alumina will fuse at between
1600°C to 1700°C, but it will sinter at a much lower temperature.
Procera (Noble Biocare) AllCeram cores were the first CAD-CAM (Computer Assisted
Design-Computer Assisted Manufactured) dental substructures made. A standard die made from an impression taken by a dentist
is digitized using a specially designed mechanical scanning device (pictured
at left) and a computer that turns the
shape of the die into digitized data. The data is then used to
fabricate an oversized die to which 99.9% pure alumina is dry pressed. The
pressed, oversize green body is then removed from the die and sintered, thus shrinking it to the
correct size and creating a hard core to which a feldspathic porcelain
veneer can be applied. Cores like this are about as strong as
In-Ceram-Zirconia (~700MPa), but the coping is said to be more translucent
and to give better esthetics. While they can be used for posterior
crowns, posterior bridges are not advised. Procera Forte is a newer
product in which the same mechanical technique is used to scan the
the model for fabrication of a milled, sintered zirconia product
which is sufficiently strong to be used as a framework for posterior
bridges. Click on the image to see more on the Procera scanner,the computerized images it creates
and some of the ceramic substructures fabricated from the process. |
Zirconium
Dioxide (zirconia) cores
(My thanks to
H &
O dental lab in Manchester NH for allowing me to tour their plant and
obtain these images.)
Lava
(3M ESPE), Cercon (dentsply), Procera Forte (Noble Biocare) and Everest (Kavo)
are all made from blocks of partially pre-sintered Yttrium stabilized zirconium dioxide.
They can be used to fabricate an
incredibly hard ceramic core (over1200MPa). This material is strong enough
to use as a framework for multi unit posterior bridges. It also has a
melting temperature of about 2700°C, so it is never used as
a completely fused ceramic. A more complete sintering of the milled core is done at
1500°C for approximately 11 hours. The images presented here
demonstrate the fabrication of a Lava zirconia coping.
Owing to the extreme hardness of the fully sintered ceramic, the
dental lab works with a highly compressed, partially sintered "green"
block of ceramic (image to the right). This is milled using the same
method as the Procera All-Ceram cores described above except that the cores are
milled substantially oversized. The reason for this is that the greenware will shrink
to exactly the correct size necessary to fit the original die during its final
sintering firing .
|
The green ceramic is delivered to the lab in a partially
sintered "green" plug, mounted in a jig especially designed to fit the
milling machine. The jig is fabricated from the same zirconium
oxide as the plug itself. The two barcodes on the jig identify the
patient, as well as the lot number of the green zirconium plug.
This information tells the milling computer the expected
shrinkage of that particular lot in order to calculate the exact size to
which the final product must be milled. This is necessary because each
lot will have slightly different shrinkage ratios when fired to its
final sintered state. The image below shows what a green
core looks like when the milling machine is finished with it.

|
| In order to mill the shape needed, the trimmed die is placed
in a special "camera" enclosure
which consists of a non-contact optical scanning system. This uses
a white light triangulation system to create an exact digital replica of
the entire surface of the die. |
 |
The net result of this exercise is the creation of a cyber-copy of the
surface topology of the die. Once digitized, the image can be rotated and
manipulated in any number of ways. The red line on the first image below
shows where the computer "thinks" the margin of the crown is (computers are
dumb!). The thin white line is drawn by the technician to correct the computer's
misconception. The image on the bottom right below shows the prep from the top
with the margin correctly positioned.

The technician then proceeds to block out all the undercuts,
round any sharp line angles and make any other corrections that will be
necessary in order for the finished coping to fully seat on the prep and not
place too much pressure on any one area. This is all done with digital
"wax" on the computer monitor.
 |
Once the milling machine has done its work, another technician
cuts off the sprues still connecting the finished green coping in
the jig. He then proceeds to thin out the marginal edges using
specially designed rubber wheels and a handpiece.
|
|
The image below shows seven crown copings and two three
unit bridge frameworks, all in a green state. The milling
machine automatically mills the walls of the copings to exactly the
correct thickness. This if fairly thin, because of the inherent
strength of the zirconia material. The thinness of the copings
leaves more room for the esthetic veneer that will overlay it,
making for a more esthetic result.
 |
|
The substructures you see in the image above are in a "baking"
tray waiting to be dipped into the coloring baths you see in the
image below. The coloring of the frameworks takes
place before the sintering process according to the prescribed
shade. There are seven possible shades, each corresponding to
the approximate color of the normal dentin of a tooth that would be the
same shade of the one prescribed by the dentist.
 |
<<--Ceramics
4--Glass ceramics
<<--Ceramics 1--The basics |